Chemical reactions in DACCM, ERW, and OAE —
The figure above shows the sequences of chemical reactions that occur as CO2 from the atmosphere is converted to minerals such as calcite (DACCM) or the chemical compound bicarbonate (ERW and OAE). The three reaction sequences are nearly identical.
In the reactions, a rock (basalt, for example) supplies positive charged An ion is an atom or molecule that has a positive or negative electric charge due to the loss or gain of one or more electrons. (called cations) such as Ca2+ and Mg2+ that balance negative charged ions (called anions) such as bicarbonate (HCO3-) and carbonate (CO32-).
The end result is the carbon atoms from CO2 in the atmosphere end up being permanently stored in calcite (DACCM) or bicarbonate (ERW and OAE).
The balance of charges between cations (+) and anions (-) result in a neutral charged solid (e.g., the mineral calcite) or a solution (e.g., HCO3- dissolved in water) — which has long-term stability.
Please note:
- The reactions shown are simplified from actual conditions.
- The reactions occur in groundwater, soil water, or ocean water, depending on the process DACCM, ERW, or OAE.
- Basalt is shown as the injection target for DACCM, but other igneous rock such as peridotite may also be an injection target.
- Basalt is shown as the feedstock for OAE, but other types of rock such as limestone (after heat treatment) may be used as a feedstock to provide positive-charged calcium ions that counterbalance the negative-charged bicarbonate ions .
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